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产品名称: Porapak Q 六氟丙烯中不凝性气体测定PQ柱
产品型号: Porapak Q
品牌: 1941
产品数量:
产品单价: 面议
日期: 2024-03-16

Porapak Q 六氟丙烯中不凝性气体测定PQ柱的详细资料

六氟丙烯中不凝性气体测定PQ柱
六氟丙烯中不凝性气体测定PQ柱 详细信息:

名称:填充柱

固定相:高分子小球

型号:Porapak Q

规格:2m*3mm

粒度:0.15mm--0.18mm

应用:GB_T 31400-2015_氟代烷烃 不凝性气体(NCG)的测定 气相色谱法

GB/T 33063-2016 制冷剂用氟代烯烃 不凝性气体(NCG)测定通用方法


六氟丙烯C3F6或CF3CFCF2
1.别名·英文名
全氟丙烯;Perfluoropropylene、pernuoropropene Hexafluoro-propene.
2.用途
生成共聚物,使共聚物增添不燃、不氧化的特性;有机合成中间体。
3.制法
(1)聚四氟乙烯分解。
(2)氯二氟甲烷热分解。
(3)1,2一二溴六氟丙烷的去溴化反应。
4.理化性质
分子量: 150.023
熔点: -156.5℃
沸点(101.325kPa): -29.6℃
液体密度(-40℃): 1583kg/m3
气体密度(101.325kPa,20℃): 6.240kg/m3
相对密度(101.325kPa,20℃,空气=1):5.18
比容(21.1℃,101.325kPa):0.161m3/kg
临界温度: 94.0℃
临界压力: 2900kPa
临界密度: 510.4kg/m3
气化热(-29.6℃): 134.503kJ/kg
蒸气压(-40.71℃): 61.727kPa
(-3.31℃): 303.033kPa
(19.74℃): 652.746kPa
粘度(气体,101.325kPa,25℃):0.0119mPa·S
导热系数(气体,101.325kPa,25℃):0.011255w/(m·K)
易燃性级别: 1
毒性级别: 0
反应活性级别: 0
六氟丙烯在常温常压下为无色不燃性气体,然而与可燃气混合点燃时,也会导致分解,放出有毒的产物。它易液化充瓶,在21.1℃时S.P.为687.4kPa。
5.毒性·安全防护
今未得到有关它的毒性数据,推荐它为微毒,低浓时可认为无毒。
在无水时六氟丙烯无腐蚀性,因而常用的金属均适用。但如与水接触,它会缓慢水解,产生腐蚀条件,为此设备和管线在使用前必须除去空气和水分。


滕州市浩瀚色谱仪器技术服务有限公司,采用气相色谱法测定制冷剂中的不凝气含量,色谱柱为PQ柱,载气为氦气,TCD检测器,结果表明选择性,重复性和再现性较好,方法简便,准确,重复性好,可用于制冷剂中不凝气含量的测定。



六氟丙烯中不凝性气体测定PQ柱 测试谱图:




PQ column for determination of non-condensable gases in hexafluoropropylene
PQ column for determination of non-condensable gases in hexafluoropropylene Details:

Name: packed column

Stationary phase: polymer beads

Model: Porapak Q

Specification: 2m * 3mm

Granularity: 0.15mm--0.18mm

Application: GB_T 31400-2015_Fluoroalkanes Determination of Non-Condensable Gases (NCG) Gas Chromatography

GB / T 33063-2016 General method for determination of non-condensable gas (NCG) for fluoroolefins for refrigerants


Hexafluoropropylene C3F6 or CF3CFCF2
1. Alias · English name
Perfluoropropylene; Perfluoropropylene, pernuoropropene Hexafluoro-propene.
2. Use
Forming copolymers, adding non-flammable and non-oxidizing properties to copolymers; organic synthesis intermediates.
3. Manufacturing method
(1) Decomposition of polytetrafluoroethylene.
(2) Thermal decomposition of chlorodifluoromethane.
(3) Debromination reaction of 1,2-dibromohexafluoropropane.
4. Physical and chemical properties
Molecular weight: 150.023
Melting point: -156.5 ℃
Boiling point (101.325kPa): -29.6 ℃
Liquid density (-40 ° C): 1583kg / m3
Gas density (101.325kPa, 20 ℃): 6.240kg / m3
Relative density (101.325kPa, 20 ℃, air = 1): 5.18
Specific volume (21.1 ℃, 101.325kPa): 0.161m3 / kg
Critical temperature: 94.0 ℃
Critical pressure: 2900kPa
Critical density: 510.4kg / m3
Gasification heat (-29.6 ℃): 134.503kJ / kg
Vapor pressure (-40.71 ° C): 61.727kPa
(-3.31 ℃): 303.033kPa
(19.74 ° C): 652.746kPa
Viscosity (gas, 101.325kPa, 25 ° C): 0.0119mPa · S
Thermal conductivity (gas, 101.325kPa, 25 ° C): 0.011255w / (m · K)
Flammability level: 1
Toxicity level: 0
Reactivity level: 0
Hexafluoropropene is a colorless and non-flammable gas at normal temperature and pressure. However, when mixed with flammable gases, it will also cause decomposition and release toxic products. It is easy to liquefy and fill bottles, and S.P. is 687.4kPa at 21.1 ℃.
5. Toxicity and safety protection
No data on its toxicity have been obtained so far, and it is recommended to be slightly toxic, and it can be considered non-toxic at low concentrations.
Hexafluoropropene is non-corrosive in the absence of water, so commonly used metals are suitable. However, if it comes into contact with water, it will slowly hydrolyze and cause corrosive conditions. Therefore, the equipment and pipeline must be removed from the air and moisture before use.


Tengzhou Haohan Chromatographic Instrument Technology Service Co., Ltd. uses gas chromatography to determine the non-condensable gas content in the refrigerant. The chromatographic column is a PQ column, the carrier gas is helium, and the TCD detector. The results show selectivity, repeatability and reproducibility. The method is simple, accurate, and repeatable. It can be used for the determination of non-condensable gas in refrigerants.



PQ column for determination of non-condensable gases in hexafluoropropylene